In 2019.0 ORG BIOMOL CHEM published article about DYNAMIC KINETIC RESOLUTION; CATALYZED ASYMMETRIC ARYLATION; H INSERTION REACTIONS; ENANTIOSELECTIVE SYNTHESIS; NUCLEOPHILIC REACTIVITIES; BROMO ARYLACETATES; INDOLES; EPOXIDES; KETOESTERS; EFFICIENT in [Kim, Yongtae; Choi, Yun Soo; Hong, Su Kyung; Park, Yong Sun] Konkuk Univ, Dept Chem, Seoul 05029, South Korea in 2019.0, Cited 56.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Recommanded Product: 150-19-6
Highly enantioenriched 2,2-diarylethanols can be efficiently synthesized through the Friedel-Crafts alkylation of (hetero) arenes with configurationally labile a-bromoarylacetates. The substitution of highly diastereoenriched a-bromoarylacetates occurs in the presence of AgOTf, and the subsequent reduction affords diverse 2,2-diarylethanols with high yields and enantioselectivities up to 99 : 1 er. In addition, the application of this asymmetric synthetic methodology to the preparation of highly enantioenriched dihydrobenzofuran and indoline derivatives is demonstrated.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles