Computed Properties of C5H9IO. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 3-(Iodomethyl)tetrahydrofuran, is researched, Molecular C5H9IO, CAS is 475060-43-6, about Bismuth Compounds in Radical Catalysis: Transition Metal Bismuthanes Facilitate Thermally Induced Cycloisomerizations. Author is Ramler, Jacqueline; Krummenacher, Ivo; Lichtenberg, Crispin.
The controlled radical chem. of Bi compounds is still in its infancy. Further developments are fueled by the properties of these complexes (e.g., low toxicity, high functional group tolerance, low homolytic bond dissociation energies, and reversible homolytic bond dissociations), which are highly attractive for applications in synthetic chem. Here the authors report the 1st catalytic application of transition metal bismuthanes (i.e. compounds with a Bi-TM bond; TM = transition metal). Using the catalyzed radical cycloisomerization of δ-iodoolefins as a model reaction, characteristics complementary or superior to known B, Mn, Cu, Zn, Sn, and alkali metal reagents are demonstrated (including a different crucial intermediate), establishing transition metal bismuthanes as a new class of (pre-)catalysts for controlled radical reactions.
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Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles