Authors Vogelsang, D; Vondran, J; Hares, K; Schafer, K; Seidensticker, T; Vorholt, AJ in WILEY-V C H VERLAG GMBH published article about CARBONYLATION REACTIONS in [Vogelsang, Dennis; Vondran, Johanna; Hares, Kevin; Schaefer, Kevin; Seidensticker, Thomas] TU Dortmund Univ, Dept Bio & Chem Engn, Lab Ind Chem, Emil Figge Str 66, D-44227 Dortmund, Germany; [Vorholt, Andreas J.] Max Planck Inst Chem Energy Convers, Stiftstr 34, D-45470 Mulheim, Germany in 2020.0, Cited 23.0. Application In Synthesis of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Palladium catalysed carboxytelomerisation of 1,3-butadiene with alcohols yields unsaturated C-9-pelargonic esters in an atom-economic and straightforward way. Although carboxytelomerisation is of current interest, limitations of applicable alcohol substrates have not been fully investigated. In here, we present the transfer of the catalytic system comprising palladium acetate and tri-n-butyl phosphine in pyridine to a broad variety of 20 alcohols with vast difference in nucleophilicity and sterical demands yielding the corresponding esters in a 100% atom economic manner. Effects of nucleophilicity and sterical demands were revealed for monoalcohols, di- and polyols. Whilst yields, chemoselectivity and E/Z-selectivity of the pelargonic acid derivatives were excellent with up to 99%, selectivity towards mono-, di- and triesters could be controlled successfully. Finally, the reaction profile of the carboxytelomerisation glycerol was uncovered, yielding up to 97% of industrially relevant unsaturated C-9-short chain fats.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles