Name: Benzyl Alcohol. Sheng, ZY; Ma, DR; He, Q; Wu, K; Yang, L in [Sheng, Zhongyi; Ma, Dingren; He, Qing; Wu, Kai; Yang, Liu] Nanjing Normal Univ, Sch Environm, Nanjing 210023, Jiangsu, Peoples R China; [Sheng, Zhongyi] Zhejiang Univ, Suzhou Ind Technol Res Inst, Suzhou 215163, Jiangsu, Peoples R China published Mechanism of photocatalytic toluene oxidation with ZnWO4: a combined experimental and theoretical investigation in 2019.0, Cited 45.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
ZnWO4 catalysts are brilliant in the field of photocatalysis due to their excellent chemical stability and optical properties. In this work, we prepared pure ZnWO4 by a hydrothermal method, evaluated its ability to degrade toluene and elucidated the photocatalytic reaction mechanism. The results showed that ZnWO4 had excellent catalytic activity and stability. Combining the ESR spectroscopy spectra and DFT calculation results, ZnWO4 was found to adsorb a large amount of O-2 and H2O, and activate them to produce active radicals participating in the oxidation reaction of toluene. The reactions to form benzyl alcohol and benzoic acid could be carried out spontaneously based on the Gibbs free energy calculation results and in situ DRIFTS spectra, which indicated that benzaldehyde can be easily converted to benzoic acid. The ring opening reaction is more likely to be carried out on benzoic acid. The findings of this work can extend the application of ZnWO4 materials and the understanding of the mechanism of photocatalytic degradation of toluene.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles