The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane, is researched, Molecular C19H18N2O2, CAS is 132098-59-0, about Enantioselective Mukaiyama-Michael reactions of 2-carbomethoxycyclopentenone catalyzed by chiral bis(oxazoline)-Cu(II) complexes, the main research direction is carbomethoxycyclopentenone stereoselective Mukaiyama Michael alkoxysilyloxypropene; copper bisoxazoline catalyst stereoselective Mukaiyama Michael.Recommanded Product: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane.
The conjugate addition of propionate silyl ketene acetal to 2-(carbomethoxy)cyclopentenone is promoted by bis(oxazoline)-Cu(II) complexes with high diastereoselectivity and good enantiomeric excesses. The absolute configuration of the product can be controlled by varying the copper counterion. A catalytic version of the reaction was developed, which gave a keto acid in 72% d.e. and 63% e.e.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles