An article Synthesis of tertiary amines by direct Bronsted acid catalyzed reductive amination WOS:000554386800027 published article about TRIFLIC ACID; EFFICIENT; ALDEHYDES; KETONES; N,N-DIMETHYLFORMAMIDE; HYDROGENATION; FORMAMIDES; AMIDATION; ALCOHOLS in [Hussein, Mohanad A.; Dinh, An H.; Thanh Vinh Nguyen] Univ New South Wales, Sch Chem, Sydney, NSW, Australia; [Huynh, Vien T.] Univ Sydney, Sch Chem, Sydney, NSW, Australia in 2020.0, Cited 56.0. The Name is 3-Hydroxybenzaldehyde. Through research, I have a further understanding and discovery of 100-83-4. COA of Formula: C7H6O2
Tertiary amines are ubiquitous and valuable compounds in synthetic chemistry, with a wide range of applications in organocatalysis, organometallic complexes, biological processes and pharmaceutical chemistry. One of the most frequently used pathways to synthesize tertiary amines is the reductive amination reaction of carbonyl compounds. Despite developments of numerous new reductive amination methods in the past few decades, this reaction generally requires non-atom-economic processes with harsh conditions and toxic transition-metal catalysts. Herein, we report simple yet practical protocols using triflic acid as a catalyst to efficiently promote the direct reductive amination reactions of carbonyl compounds on a broad range of substrates. Applications of this new method to generate valuable heterocyclic frameworks and polyamines are also included.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles