Norouzi, M; Elhamifar, D in [Norouzi, Meysam; Elhamifar, Dawood] Univ Yasuj, Dept Chem, Yasuj 7591874831, Iran published Ionic liquid-modified magnetic mesoporous silica supported tungstate: A powerful and magnetically recoverable nanocatalyst in 2019.0, Cited 71.0. Safety of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
In this study, a novel ionic liquid-modified magnetic mesoporous silica supported tungstate (Fe3O4@MCM@IL-WO4=) with core-shell structure is prepared, characterized and applied as recoverable catalyst in the green oxidation of alcohols. The magnetic mesoporous Fe3O4@MCM material was prepared through surfactant directed modification of magnetic iron oxides with tetramethoxysilane. The Fe3O4@MCM@EL-W-4(=) nanocatalyst was then prepared via chemical attachment of alkyl imidazolium chloride on Fe3O4@MCM followed by treatment with sodium tungstate. This catalyst was characterized using FT-IR spectroscopy, TG, EDX, low-angle and wide-angle PXRD, SEM, VSM and nitrogen adsorption-desorption analyses. The Fe3O4@MCM@IL-WO4= was applied as powerful catalyst in the green oxidation of alcohols using hydrogen peroxide oxidant under ultrasonic conditions. The corresponding carbonyl products were obtained in high yield and selectivity. The reusability, recoverability and durability of this catalyst have also been studied under applied conditions.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles