An article Screening of the Au:Pt Atomic Ratio Supported in SrCO3: Effects in the Performance of the Solvent-Free Oxidation of Benzyl Alcohol WOS:000511995800007 published article about CRYSTALLOGRAPHY OPEN DATABASE; OPEN-ACCESS COLLECTION; SELECTIVE OXIDATION; GOLD NANOPARTICLES; CATALYSTS; METAL; PLATINUM; GLYCEROL; CRYSTAL; OXIDE in [Batista, Francisco S. C. L.; Melo, Itaciara E. M. S.; Pereira, Laise N. S.; Lima, Alexia G. P.; Costa, Jean C. S.; Magalhaes, Janildo L.; Moura, Carla V. R.; Garcia, Marco A. S.; Moura, Edmilson M.] Univ Fed Piaui, Dept Quim, BR-64049550 Teresina, PI, Brazil; [Bashal, Ali H.] Taibah Univ, Fac Sci, Dept Chem, Al Madinah Al Mounawara 30002, Saudi Arabia; [Lima, Francisco C. A.] Univ Fed Piaui, Programa Posgrad Biotecnol RENORBIO, BR-64049550 Teresina, PI, Brazil; [Lima, Francisco C. A.] Univ Estadual Piaui, Lab Quant Computac & Planejamento Farmacos, BR-64002150 Teresina, PI, Brazil in 2020, Cited 46. HPLC of Formula: C7H8O. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
We have prepared, by a sol-immobilization method, bimetallic catalysts with different Au:Pt atomic ratios supported on commercial SrCO3. The catalytic performance for the oxidation reaction of benzyl alcohol of such materials was compared to the monometallic counterparts. aiming at the obtaining of the best composition of the material. It was found that the Au:Pt atomic ratio presents a remarkable effect on the system performance, i.e., Pt-rich systems arc more selective; however, less active. Thus, an equilibrium related to the activity and selectivity of the system was obtained by considering the yield of the system. Also, some density functional theory (DFT) insights were obtained by using a cluster of 14 atoms of Au and 1 or 2 atoms of Pt. X-ray photoelectron spectroscopy, elemental mapping in scanning transmission electron microscopy before and after catalyst usage, flame atomic absorption spectroscopy, Rietveld refinement, among other techniques, were used and associated to the experimental data, which allowed us to propose a catalytic mechanism for the system, which was important since SiCO3 has not been considered before as catalyst support for alcohol oxidation reactions.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles