Koyanagi, Takaoki; Herath, Ananda; Chong, Ashley; Ratnikov, Maxim; Valiere, Andrew; Chang, Jim; Molteni, Valentina; Loren, Jon published the article 《One-Pot Electrochemical Nickel-Catalyzed Decarboxylative Sp2-Sp3 Cross-Coupling》. Keywords: sodium alkyl carboxylate aryl iodide hydroxyphthalimide tetramethyluronium hexafluorophosphate; nickel catalyst one pot electrochem decarboxylative reductive cross coupling; alkyl arene preparation.They researched the compound: Nickel(II) chloride ethylene glycol dimethyl ether complex( cas:29046-78-4 ).Recommanded Product: Nickel(II) chloride ethylene glycol dimethyl ether complex. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:29046-78-4) here.
A one-pot electrochem. nickel-catalyzed decarboxylative sp2-sp3 cross-coupling reaction has been developed using redox-active esters prepared in situ from alkyl carboxylates and N-hydroxyphthalimide tetramethyluronium hexafluorophosphate (PITU). This undivided cell one-pot method enables C-C bond formation using inexpensive, benchtop-stable reagents with isolated yields up to 95% with good functional group tolerance, which includes nitrile, ketone, ester, alkene and selectivity over other aromatic halogens.
In some applications, this compound(29046-78-4)Recommanded Product: Nickel(II) chloride ethylene glycol dimethyl ether complex is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles