Saha, T; Pramanick, R; Sengupta, D; Goswami, S in [Saha, Tanushri; Pramanick, Rajib; Sengupta, Debabrata; Goswami, Sreebrata] Indian Assoc Cultivat Sci, Sch Chem Sci, Kolkata 700032, India published Metal-ligand cooperativity in a ruthenium(II) complex of bis-azoaromatic ligand for catalytic dehydrogenation of alcohols in 2019.0, Cited 46.0. Category: indole-building-block. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Herein a new Ru-phosphine complex (1) with molecular formula [RuL(PPh3)Cl-2] is reported where L is a redox active pincer ligand 2,6-bis(phenylazo)pyridine. The isolated complex has been characterized by usual spectroscopic techniques including single crystal X-ray crystallographic analysis. Complex 1 efficiently catalyzes aerobic oxidation of a wide range of primary and secondary benzylic, allylic, heterocyclic, alicyclic alcohols under mild conditions and is found to be superior over several other Ru (0, +2 and + 3), Ru-H and Ru-PPh3 catalysts. Mechanistic studies indicate that a transient Ru-H intermediate is formed in the catalytic cycle which gets switched into a Ru-hydrazo intermediate via hydrogen-walking mechanism. The catalyst is regenerated by aerial oxidation producing H2O2 as a by-product.
Category: indole-building-block. Welcome to talk about 100-51-6, If you have any questions, you can contact Saha, T; Pramanick, R; Sengupta, D; Goswami, S or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles