Authors Mardani, A; Kazemi, F; Kaboudin, B in ELSEVIER SCIENCE SA published article about VISIBLE-LIGHT IRRADIATION; AEROBIC OXIDATION; TETRABUTYLAMMONIUM TRIBROMIDE; SOLVENT-FREE; PHOTOCATALYTIC OXIDATION; AMMONIUM TRIBROMIDES; SELECTIVE OXIDATION; PHOTOOXIDATION; ALCOHOLS; BENZALDEHYDE in [Mardani, Atefeh; Kazemi, Foad; Kaboudin, Babak] Inst Adv Studies Basic Sci IASBS, Dept Chem, POB 45195-1159, Zanjan, Iran; [Kazemi, Foad] Inst Adv Studies Basic Sci IASBS, Ctr Climate & Global Warming CCGW, Zanjan 4513766731, Iran in 2021, Cited 56. Application In Synthesis of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
In this report, tetrabutylammonium tribromide (TBATB) was introduced as an efficient visible light active catalyst to carry out the aerobic oxidation of toluene, its derivatives, and some of methyl arenes to benzaldehydes, benzoic acids and ketones in good to high yields. All the oxidation reactions were performed under mild conditions using oxygen as a green oxidant, a catalytic amount of TBATB under blue (460 nm), royal blue (430 nm), and violet LED (400 nm) irradiation. It was found that the reactions selectivity was significantly affected by changing the solvent (from CH3CN to EtOAc) and LED wavelength (from blue to violet). In the following, our mechanistic studies revealed that the visible light oxidation of toluenes and methyl arenes over TBATB could be following a benzyl peroxy radical intermediate.
Application In Synthesis of Benzyl Alcohol. Welcome to talk about 100-51-6, If you have any questions, you can contact Mardani, A; Kazemi, F; Kaboudin, B or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles