Simple exploration of Methyl 1H-indole-5-carboxylate

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Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 1011-65-0, molcular formula is C10H9NO2, introducing its new discovery. Recommanded Product: 1011-65-0

Bronsted acid catalyzed friedel-crafts alkylation reactions of trifluoromethyl-alpha,beta-ynones with indoles

The successful development of a Bronsted acid catalyzed Friedel-Crafts alkylation reaction between trifluoromethyl-alpha,beta-ynones and indoles has been described. The reaction is catalyzed by benzoic acid (5 mol%), with the indoles adding to the carbonyl carbon of the trifluoromethyl-alpha,beta- ynones producing the corresponding 1,2-addition products as trifluoromethyl propargyl alcohols in high yields. Furthermore, treatment of the product with indoles in the presence of trifluoroacetic acid (10 mol%) afforded trifluoromethyl-functionalized unsymmetrical bis(indolyl)propynes in high yields.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles