An article Alcohols selective oxidation with H2O2 catalyzed by robust heteropolyanions intercalated in ionic liquid-functionalized graphene oxide WOS:000582701400055 published article about EFFICIENT HETEROGENEOUS EPOXIDATION; HYDROGEN-PEROXIDE; BENZYL ALCOHOL; POLYOXOMETALATE; NANOPARTICLES; HYBRID; IMMOBILIZATION; MONOLITH; ALKENES in [Zheng, Weiguo; Wu, Min; Yang, Chen] Hunan Univ Arts & Sci, Hunan Prov Cooperat Innovat Ctr Construct & Dev D, Hunan Prov Engn Res Ctr Electroplating Wastewater, Coll Chem & Mat Engn,Hunan Prov Key Lab Water Tre, Changde 415000, Peoples R China; [Chen, Yaju] Guangdong Univ Petrochem Technol, Sch Chem, Maoming 525000, Peoples R China; [Tan, Rong; Yin, Donghong] Hunan Normal Univ, Natl & Local Joint Engn Lab New Petrochem Mat & F, Minist Educ, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Peoples R China in 2020.0, Cited 51.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Recommanded Product: Benzyl Alcohol
A set of heteropolyacid-based ionic heterogeneous catalysts (PW@IL-GO(m)) have been synthesized by intercalated heteropolyanions in ionic liquid (IL)-functionalized graphene oxide (GO) via amino-protonation and/or anion-exchange reaction. This immobilization method offered improved dispersity, accessibility and stability of active sites. The amphipathic nature of IL-GO sheets and porosity of PW@IL-GO(m) are beneficial to reducing mass transfer limitation in a water/organic substrate two-phase system. Then, these obtained hybrids were employed as efficient and robust catalysts for the selective oxidation of alcohols into carbonyl compounds using hydrogen peroxide as an oxidant under organic solvent-free condition. As expected, PW@IL-GO(m) catalysts showed even much better activity than the corresponding homogeneous HPW (phosphotungstic acid) catalyst. Particularly, PW@IL-GO(1.5) gave a benzyl alcohol conversion of 94% and benzaldehyde chemoselectivity of 91%. Moreover, owing to the heterogeneous nature and strong cation-anion interactions between cationic supporter and PW anions, the as-prepared catalyst presented advantages of convenient recovery, simple preparation and steady reuse, further providing the industrial application potential in sustainable oxidation reactions.
About Benzyl Alcohol, If you have any questions, you can contact Zheng, WG; Wu, M; Yang, C; Chen, YJ; Tan, R; Yin, DH or concate me.. Recommanded Product: Benzyl Alcohol
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles