Recommanded Product: 123-11-5. Recently I am researching about S-SUBSTITUTED ALDEHYDES; ALKYNE HYDROACYLATION; ALLYLIC ALCOHOLS; COUPLING REACTION; C-H; ALKENE; CYCLIZATION; MECHANISM; SCOPE; ACID, Saw an article supported by the Natural Science Foundation of Shandong ProvinceNatural Science Foundation of Shandong Province [ZR2019MB003]; Key Research and Development Program of Shandong Province [2018GGX109010]; High-Level Project Cultivation Program of TSMC [2018GCC16]; Academic Promotion Programme of Shandong First Medical University [2019LJ003]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: You, GR; Chang, ZX; Yan, JZ; Xia, CC; Li, FR; Li, HS. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde
A rhodium-catalyzed tandem intermolecular hydroacylation of terminal alkyne-substituted secondary alcohols with chelating aldehydes and deconjugative isomerization of the resulting alpha,beta-unsaturated ketones for the preparation of synthetically valuable 1,4-diketones is developed. Of note, the completely atom-economical protocol can be extended to the alkynyl alcohols with appropriate carbon chain length, from which 1,5-diketone and 1,6-diketone were obtained involving the short-range deconjugative isomerization. Given its robustness, broad substrate scope, and excellent regioselectivity, this approach provides a promising platform for the synthesis of diverse diketones.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles