Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 132098-59-0, is researched, SMILESS is C1(CC2=N[C@@H](C3=CC=CC=C3)CO2)=N[C@@H](C4=CC=CC=C4)CO1, Molecular C19H18N2O2Journal, Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) called Heterogeneous catalysts for asymmetric hydrogenation of enamides using molecular imprinting technology, Author is Liu, Xiao-Chuan; Lee, Justine; Bernard, Steven, the main research direction is heterogeneous catalyst asym hydrogenation enamides mol imprinting.Reference of Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane.
We have successfully synthesized a new class of heterogeneous catalysts for asym. hydrogenation of enamides combining transition metal catalysis and mol. imprinting technol. These new catalysts are MIPs made from rhodium (I) and copper (II) complexes with the bis(oxazoline) chiral ligands. One of the Rh-MIPs showed 87% ee toward L- enantiomeric product while the Cu-MIP showed 82% ee toward D- enantiomeric product. Both MIPs are easy to sep. and reusable.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles