In an article, author is Qiu, Zhongxuan, once mentioned the application of 1716-12-7, Recommanded Product: Sodium 4-phenylbutanoate, Name is Sodium 4-phenylbutanoate, molecular formula is C10H11NaO2, molecular weight is 186.18, MDL number is MFCD00800247, category is indole-building-block. Now introduce a scientific discovery about this category.
A series of indane-based phosphine-oxazoline ligands with a spirocarbon stereogenic center were examined for palladium-catalyzed asymmetric allylic alkylation of indoles. Under optimized conditions, high yields (up to 98%) and enantioselectivities (up to 98% ee) were obtained with a broad scope of indole derivatives. The ligand was determined to be the most efficient P,N-ligand for this reaction. Moreover, the ligand was also efficient for Pd-catalyzed asymmetric allylic etherification with hard aliphatic alcohols as nucleophiles.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles