Product Details of 2208-59-5. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 2-(Pyridin-4-yl)-1H-benzo[d]imidazole, is researched, Molecular C12H9N3, CAS is 2208-59-5, about Syntheses, Crystal Structures, and Properties of a Series of Coordination Polymers Based on 2-(n-Pyridyl)benzimidazole Ligands (n = 3, 4). Author is Wang, Cheng-Jun; Yue, Ke-Fen; Tu, Zhen-Xing; Xu, Li-Li; Liu, Yong-Liang; Wang, Yao-Yu.
Six new coordination polymers, namely, [Zn(3-PyHBIm)(oba)H2O] (1), [Cd(3-PyHBIm)(oba)H2O] (2), [Ni(3-PyHBIm)(oba)H2O]·3H2O (3), [Zn(4-PyHBIm)(oba)] (4), [Cd(4-PyHBIm)2(oba)]·H2O(5), and [Co(4-PyHBIm)2(oba)]·H2O (6) were synthesized under hydrothermal conditions (3-PyHBIm = 2-(3-pyridyl)benzimidazole; 4-PyHBIm = 2-(4-pyridyl)benzimidazole; oba = 4,4′-oxybis(benzoate)). The compounds were characterized by single crystal x-ray diffraction, IR, and thermogravimetric and elemental analyses. Compounds 1 and 2 contain simple one-dimensional (1D) polymeric chains assembled into a three-dimensional (3D) network through aromatic π-π stacking interactions and hydrogen bonding interactions. Compound 3 contains 1D polymeric chains with side arms which assembled into a two-dimensional (2D) network with channels and further assembled into a 3D network through C-H···π interactions. Compounds 4 and 5 form 1D mol. ladder coordination polymers. Compound 6 consists of 2D coordination networks with 2-fold interpenetration. The luminescence properties of 1, 2, 4, and 5 were studied in the solid state at room temperature
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles