In 2019 ORG LETT published article about 3-AMINOCHROMAN DERIVATIVES; INTERRUPTED PUMMERER; ARYL SULFOXIDES; INTRAMOLECULAR CAPTURE; OXIDATIVE BROMINATION; QUINONE METHIDES; SWERN OXIDATION; ALPHA-ARYLATION; LEWIS-ACIDS; PHENOLS in [Acosta-Guzman, Paola; Rodriguez-Lopez, Alvaro; Gamba-Sanchez, Diego] Univ Andes, Dept Chem, Lab Organ Synth Bio & Organocatalysis, Cra 1 18A-12 Q 305, Bogota 111711, Colombia in 2019, Cited 77. The Name is 3-(Trifluoromethyl)phenol. Through research, I have a further understanding and discovery of 98-17-9. Application In Synthesis of 3-(Trifluoromethyl)phenol
The competition between an unprecedented reductive chlorination and the Pummerer reaction was studied and applied to the synthesis of benzofused oxygen heterocycles including 3-aminochromanes and in the intramolecular chlorination of activated aromatic rings. The use of (COCl)(2) as a Pummerer activator showed substantial activity, producing alpha-chlorinated sulfides that can undergo Pummerer-Friedel-Crafts cyclization. If the aromatic ring has electron-donating groups in position three, then the reaction follows a different pathway, yielding the reductive chlorination products, where the chlorine atom comes from a sulfonium salt.
Application In Synthesis of 3-(Trifluoromethyl)phenol. Bye, fridends, I hope you can learn more about C7H5F3O, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles