Formula: C7H8O. In 2020.0 ACS APPL MATER INTER published article about CHROMOPHORE-CATALYST ASSEMBLIES; WATER-OXIDATION; ORGANIC SENSITIZERS; SINGLE-SITE; PORPHYRIN in [Shan, Bing; Nayak, Animesh; Wu, Lei; Meyer, Thomas J.] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA; [Badgurjar, Deepak; Chitta, Raghu] Cent Univ Rajasthan, Dept Chem, Sch Chem Sci & Pharm, Kishangarh 305817, India in 2020.0, Cited 41.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
The synthesis, characterization, and electrochemical and photophysical properties of the phosphonate-derivatized carbazole (CBZ) and boron dipyrromethene (BODIPY) chromophores in the dyes, BODIPY(CBZ)(2)PO3H2 (8) and BODIPY(Tol)(2)PO3H2 (7), are described. The oxide-bound dyes have been explored as light absorbers in dyesensitized photoelectrosynthesis cell (DSPEC) applications. The BODIPY-CBZ phosphonate ester (6) features a broad, intense UV-visible absorption spectrum with absorptions at 297 and 650 nm that arise from mixed transitions at the CBZ and BODIPY units. Electrochemical measurements on BODIPY(CBZ)(2)Br (4) in 0.1 M [nBu(4)N] [PF6] in dichloromethane, vs normal hydrogen electrode (NHE), reveal reversible oxidations at 1.19 and 1.41 V and a reversible reduction at -0.59 V. On indium tin oxide (ITO) and TiO2, a reversible one-electron oxidation appears for 7 at 0.86 and 0.90 V vs NHE in dichloromethane, respectively, which demonstrates the redox stability on metal oxide surfaces. The results of nanosecond transient absorption measurements on SnO2/TiO2 electrodes provide direct evidence for excited-state electron injection into the conduction band of TiO2 following 590 nm excitation. A longer lifetime for 8(+) compared to 7(+) is consistent with extensive intramolecular charge separation between the CBZ and BODIPY units on the surface. Photoelectrochemical studies on 8 on a SnO2/TiO2 photoanode resulted in sustained photocurrents with current maxima of similar to 200 mu A/cm(2) with hydroquinone added as a reductant under 1 sun (AM1.5 100 mWcm(-2)) illumination at pH 4.5 in 0.1 M acetate buffer and 0.4 M LiClO4. On mixed SnO2/TiO2 electrode surfaces, with the added catalyst [Ru(Mebimpy)((4,4′-(OH)(2)PO-CH2)(2)bpy)(OH2)](2+) and chromophores 7 and 8, addition of 0.1 M benzyl alcohol resulted in sustained photocurrents of 12 and 35 mu A/cm(2), consistent with oxidation to benzaldehyde.
Formula: C7H8O. Welcome to talk about 100-51-6, If you have any questions, you can contact Badgurjar, D; Shan, B; Nayak, A; Wu, L; Chitta, R; Meyer, TJ or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles