Category: indole-building-block. In 2020.0 TETRAHEDRON published article about PRELIMINARY PHARMACOLOGICAL EVALUATION; HECK-OXYARYLATION; DERIVATIVES; OXYPHENYLATION; EFFICIENT; RING in [Gaspar, Francisco V.; Barcellos, Julio C. F.; Civicos, Jose F.; Costa, Paulo R. R.] Univ Fed Rio de Janeiro, Inst Pesquisas Prod Nat, Lab Quim Bioorgan, Ctr Ciencias Saude, Bloco H,Ilha Cidade Univ, BR-21941590 Rio De Janeiro, RJ, Brazil; [Merino, Pedro] Univ Zaragoza, Inst Biocomp & Fis Sistemas Complejos BIFI, Fac Ciencias, Campus San Francisco, E-50009 Zaragoza, Spain; [Najera, Carmen] Univ Alicante, Ctr Innovac Quim Avanzada ORFEO CINQA, Apdo 99, Alicante 03080, Spain in 2020.0, Cited 33.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.
The oxyarylation of alkoxy-2H-chromenes (1a-e) with o-iodophenols substituted by electron-withdrawing (CHO) and electron-donating (OMe) groups is studied under two experimental conditions: a) Pd(OAc)(2), Ag2CO3 in PEG-400 at 140 degrees C, 10 min and b) oxime-based palladacycle, DIPEA, in PEG-400 at 150 degrees C, 3-4 h. Pterocarpans are obtained in moderate to good chemical yields. (C) 2020 Published by Elsevier Ltd.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles