Tag: M.W=100-150

I found the field of Chemistry very interesting. Saw the article Bronsted acid-catalyzed synthesis of tetrasubstituted allenes and polysubstituted 2H-chromenes from tertiary propargylic alcohols published in 2019. Application In Synthesis of m-Methoxyphenol, Reprint Addresses Sanz, R (corresponding author), Univ Burgos, Fac Ciencias, Dept Quim, Area Quim Organ, Pza Misael Banuelos S-N, Burgos 09001, Spain.; Fernandez-Rodriguez, MA (corresponding author), Univ Alcala De Henares, Fac Farm, Dept Quim Organ & Quim Inorgon, Campus Cient Tecnol,Autovia A-2,Km 33-1, Madrid 28805, Spain.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

A practical and environmentally benign Bronsted acid-catalyzed protocol for the preparation of all-carbon tetrasubstituted allenes, consisting in the direct S-N’ addition of tri- or dimethoxy arenes or allyltrimethylsilane to tertiary propargylic alcohols, has been developed. In addition, a straightforward synthesis of densely substituted 2H-chromenes by metal-free tandem allenylation/heterocyclization reaction of methoxyphenols and tertiary alkynols is presented. (C) 2019 Elsevier Ltd. All rights reserved.

Application In Synthesis of m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Cabrera-Lobera, N; Velasco, N; Sanz, R; Fernandez-Rodriguez, MA or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

HPLC of Formula: C7H6O2. Smith, JB; Camp, AM; Farquhar, AH; Kerr, SH; Chen, CH; Miller, AJM in [Smith, Jacob B.; Camp, Andrew M.; Farquhar, Alexandra H.; Kerr, Stewart H.; Chen, Chun-Hsing; Miller, Alexander J. M.] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA published Organometallic Elaboration as a Strategy for Tuning the Supramolecular Characteristics of Aza-Crown Ethers in 2019.0, Cited 58.0. The Name is 3-Hydroxybenzaldehyde. Through research, I have a further understanding and discovery of 100-83-4.

Outfitting an aza-crown ether with an organotransition-metal pendant provides a mechanism for tuning its supramolecular properties. The binding affinity can be tuned by more than 2 orders of magnitude by changing the identity of the transition metal-center, altering the overall charge of the complex, or engaging in organometallic ligand substitution reactions. High Li+ selectivity (up to 29-fold higher affinity in comparison to Na+), proton-responsive behavior, and ion pair (ditopic) binding capabilities are observed in the metallacrown ethers.

About 3-Hydroxybenzaldehyde, If you have any questions, you can contact Smith, JB; Camp, AM; Farquhar, AH; Kerr, SH; Chen, CH; Miller, AJM or concate me.. HPLC of Formula: C7H6O2

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

In 2019.0 CHEM-EUR J published article about NUCLEOPHILIC-SUBSTITUTION REACTIONS; ARMED GLYCOSYL DONORS; N-PENTENYL GLYCOSIDES; RESTRICTION STRATEGY; OXOCARBENIUM IONS; PROTECTING GROUPS; REACTIVITY; MECHANISMS; ACETALS in [Panza, Matteo; Yasomanee, Jagodige P.; Demchenko, Alexei, V] Univ Missouri, Dept Chem & Biochem, One Univ Blvd, St Louis, MO 63121 USA; [Civera, Monica; Belvisi, Laura] Univ Milan, Dept Chem, I-20133 Milan, Italy in 2019.0, Cited 50.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Formula: C7H8O

Presented herein is a study of the conformation and reactivity of highly reactive thioglycoside donors. The structural studies have been conducted using NMR spectroscopy and computational methods. The reactivity of these donors has been investigated in bromine-promoted glycosylations of aliphatic and sugar alcohols. Swift reaction times, high yields, and respectable 1,2-cis stereoselectivity were observed in a majority of these glycosylations.

Formula: C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Panza, M; Civera, M; Yasomanee, JP; Belvisi, L; Demchenko, AV or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Rational design of ordered Pd-Pb nanocubes as highly active, selective and durable catalysts for solvent-free benzyl alcohol oxidation WOS:000465361800069 published article about NANOPARTICLES; PALLADIUM; EFFICIENT; OXYGEN; HYDROGENATION; PLATINUM in [Tang, Chongyang; Zhang, Nan; Xiao, Xiangheng] Wuhan Univ, Minist Educ, Hubei Nucl Solid Phys Key Lab, Dept Phys, Wuhan 430072, Hubei, Peoples R China; [Tang, Chongyang; Zhang, Nan; Xiao, Xiangheng] Wuhan Univ, Minist Educ, Hubei Nucl Solid Phys Key Lab, Key Lab Artificial Micro & Nanostruct, Wuhan 430072, Hubei, Peoples R China; [Tang, Chongyang; Zhang, Nan; Shao, Qi; Huang, Xiaoqing] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China in 2019.0, Cited 35.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Safety of Benzyl Alcohol

The selective oxidation of alcohols is an important chemical process with many potential applications in fine-chemical synthesis, however, the catalysts reported so far generally suffer from low activity and poor selectivity. We present here a class of ordered Pd3Pb nanocubes (NCs) with an intermetallic phase and well-defined surface as unique catalysts for selective oxidation of benzyl alcohol to benzaldehyde. The optimized Pd3Pb NCs exhibit both enhanced activity with the turnover frequency of 191 000 h(-1) and excellent selectivity up to 91.0%, outperforming the Pd3Pb/Pd NCs and Pd3Pb nanoparticles (NPs) as well as Pd NPs. The Pd3Pb NCs show increased activity in the initially consecutive reaction cycles and do not suffer from distinct deactivation thereafter. X-ray photoelectron spectroscopy reveals that the high ratio of Pd2+ to Pd-0 in the surface of Pd-Pb NPs enhances the benzaldehyde productivity, and the electronic modification of the Pd3Pb NCs boosts the benzaldehyde selectivity. Attenuated total reflectance infrared spectra further confirms that the weak benzaldehyde absorption on the Pd3Pb surface results in high selectivity of benzaldehyde.

Safety of Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Tang, CY; Zhang, N; Shao, Q; Huang, XQ; Xiao, XH or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

In 2019.0 EUR J ORG CHEM published article about OXIDATIVE TRIFLUOROMETHYLATION; H TRIFLUOROMETHYLATION; MEDIATED TRIFLUOROMETHYLATION; AROMATIC-COMPOUNDS; LACCASE; ARENES; FLUORINE; REAGENT; HETEROARENES; REACTIVITY in [Pletz, Jakob; Koeberl, Christoph; Fuchs, Michael; Kroutil, Wolfgang] Karl Franzens Univ Graz, Inst Chem, NAWI Graz, BioTechMed Graz, Heinrichstr 28, A-8010 Graz, Austria; [Steiner, Oliver; Goessler, Walter] Karl Franzens Univ Graz, Inst Chem, NAWI Graz, Univ Pl 1-1, A-8010 Graz, Austria in 2019.0, Cited 54.0. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4. HPLC of Formula: C8H8O2

Fluorination and trifluoromethylation are indispensable tools in the preparation of modern pharmaceuticals and APIs. Herein we present a concept for the introduction of a trifluoromethyl group into unprotected phenols employing catalytic copper(I) iodide and hydroquinone, tBuOOH, and the Langlois’ reagent. The method proceeds under mild conditions and exhibits an extended substrate scope compared to the biocatalytic trifluoromethylation using laccase from Agaricus bisporus. Various functional groups such as aldehydes, esters, ethers, ketones and nitriles were tolerated. The hydroquinone-mediated trifluoromethylation reaction allowed accessing trifluoromethylated phenols, which are cumbersome to prepare via previously known chemical methods.

HPLC of Formula: C8H8O2. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Pletz, J; Koeberl, C; Fuchs, M; Steiner, O; Goessler, W; Kroutil, W or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Structural Requirements of Benzofuran Derivatives Dehydro-delta- and Dehydro-epsilon-Viniferin for Antimicrobial Activity Against the Foodborne Pathogen Listeria monocytogenes WOS:000529890200264 published article about 2,3-DISUBSTITUTED BENZOFURANS; RESVERATROL; ANALOGS in [Catinella, Giorgia; Mattio, Luce M.; Musso, Loana; Arioli, Stefania; Mora, Diego; Pinto, Andrea; Dallavalle, Sabrina] Univ Milan, Dept Food Environm & Nutr Sci DeFENS, Via Celoria 2, Milan 20133, Italy; [Beretta, Giovanni Luca; Zaffaroni, Nadia] Fdn IRCCS Ist Nazl Tumori, Dept Appl Res & Technol Dev, Mol Pharmacol Unit, Via Amadeo 42, Milan, Italy in 2020.0, Cited 24.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. SDS of cas: 150-19-6

In a recent study, we investigated the antimicrobial activity of a collection of resveratrol-derived monomers and dimers against a series of foodborne pathogens. Out of the tested molecules, dehydro-delta-viniferin and dehydro-epsilon-viniferin emerged as the most promising derivatives. To define the structural elements essential to the antimicrobial activity against the foodborne pathogen L. monocytogenes Scott A as a model Gram-positive microorganism, the synthesis of a series of simplified benzofuran-containing derivatives was carried out. The systematic removal of the aromatic moieties of the parent molecules allowed a deeper insight into the most relevant structural features affecting the activity. While the overall structure of compound 1 could not be altered without a substantial loss of antimicrobial activity, the structural simplification of compound 2 (minimal inhibitory concentration (MIC) 16 mu g/mL, minimal bactericidal concentration (MBC) >512 mu g/mL) led to the analogue 7 with increased activity (MIC 8 mu g/mL, MBC 64 mu g/mL).

SDS of cas: 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Catinella, G; Mattio, LM; Musso, L; Arioli, S; Mora, D; Beretta, GL; Zaffaroni, N; Pinto, A; Dallavalle, S or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

I found the field of Chemistry; Materials Science very interesting. Saw the article Facile synthesis of hydrothermally stable mesoporous ZSM-5 zeolite from Al- SBA-16 via steam assisted crystallization published in 2020. Name: Benzyl Alcohol, Reprint Addresses Cheralathan, KK (corresponding author), VIT, Sch Adv Sci, Dept Chem, Vellore 632014, Tamil Nadu, India.. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol

In this work, Al grafted SBA-16 (Al-SBA-16) is converted into a fully crystalline hierarchical mesoporous ZSM-5 zeolite with hydrothermal stability by steam assisted crystallization under controlled conditions. The secondary mesoporosity is due to reorganization and recrystallization events happening upon steaming the precursor. Two mesoporous aluminosilicates (Al-SBA-16s) are used as the precursors of zeolites. The precursors are obtained by post-synthetic Al grafting on the silica walls of SBA-16 with aluminium isopropoxide and sodium aluminate. Mesoporous ZSM-5 zeolites obtained from the Al-SBA-16 precursors and commercial ZSM-5 are characterized using XRD, XRF, FT-IR, TEM, N-2 adsorption, Al-27 and Si-29 MAS NMR, and TPD of NH3. The results indicated the presence of intraparticle mesoporosity in the prepared mesoporous zeolites and they have comparable crystallinity with commercial ZSM-5. Catalytic activity of the synthesized mesoporous zeolites in benzylation of mesitylene is found to be comparatively more than commercial ZSM-5, which shows existence of micro/meso hierarchical structure in the mesoporous ZSM-5 zeolites. The aluminium sources, aluminium isopropoxide and sodium aluminate have a remarkable influence on the textural, acidity, and hydrothermal stability characteristics of the synthesized mesoporous ZSM-5 zeolites.

About Benzyl Alcohol, If you have any questions, you can contact Kamil, MSM; Cheralathan, KK or concate me.. Name: Benzyl Alcohol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Name: 4-Methoxybenzaldehyde. Authors Tang, YC; Yang, M; Wang, FF; Hu, X; Wang, G in PERGAMON-ELSEVIER SCIENCE LTD published article about in [Tang, Yucai; Yang, Meng; Wang, Feifei; Hu, Xia; Wang, Gang] Hunan Univ Arts & Sci, Coll Chem & Mat Engn, Hunan Prov Cooperat Innovat Ctr Construct & Dev D, Changde 415000, Peoples R China; [Tang, Yucai] Hunan Prov Key Lab Water Treatment Funct Mat, Changde 415000, Peoples R China; [Tang, Yucai] Hunan Prov Engn Res Ctr Electroplating Wastewater, Changde 415000, Peoples R China in 2021.0, Cited 42.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5

A facile I2O5 induced radical relay addition/cyclization of activated alkenes with sulfonylhydrazides has been successfully developed, leading to a broad range of sulfonylated benzimidazo[2,1-a]isoquinolin-6 (5H)-ones in moderate to good yields. The protocol has advantages of a metal-, base-, acid-, peroxide-free process, simple operation, and broad functional group tolerance. (C) 2021 Elsevier Ltd. All rights reserved.

About 4-Methoxybenzaldehyde, If you have any questions, you can contact Tang, YC; Yang, M; Wang, FF; Hu, X; Wang, G or concate me.. Name: 4-Methoxybenzaldehyde

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

I found the field of Chemistry; Pharmacology & Pharmacy very interesting. Saw the article A new fatty acid ester from Nigella sativa var. hispidula Boiss showing potent anti-protein tyrosine phosphatase 1B activity published in 2019.0. SDS of cas: 99-93-4, Reprint Addresses Xin, XL (corresponding author), Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zone, Urumqi, Peoples R China.; Xin, XL (corresponding author), Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, State Key Lab Basis Xinjiang Indigenous Med Plant, Urumqi, Peoples R China.. The CAS is 99-93-4. Through research, I have a further understanding and discovery of 4′-Hydroxyacetophenone

A new fatty acid ester (1) and seven known phenolic compounds, i.e. salfredin B-11 (2), nigephenol C (3), nigephenol B (4), acetovanillion (5), p-hydroxybenzoic acid (6), p-hydroxy-acetophenone (7) and p-hydroxybenzaldehyde (8), were isolated from the seeds of Nigella sativa var. hispidula. Among them, compounds 5, 7 and 8 were isolated from Nigella for the first time. Their structures were elucidated with HR-ESI-MS, 1D and 2D NMR spectra. Evaluation of the isolated compounds on protein tyrosine phosphatase (PTP1B) assay indicated that although compounds 2-8 show no promising anti-PTP1B activities, compound 1 possess anti-PTP1B activity with an IC50 value of 7.38 +/- 0.14 mu M in vitro. [GRAPHICS] .

SDS of cas: 99-93-4. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Liu, XX; Aisa, HA; Xin, XL or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Name: 3-Hydroxybenzaldehyde. I found the field of Chemistry very interesting. Saw the article Efficient atom-economic one-pot multicomponent synthesis of benzylpyrazolyl coumarins and novel pyrano[2,3-c]pyrazoles catalysed by 2-aminoethanesulfonic acid (taurine) as a bio-organic catalyst published in 2019.0, Reprint Addresses Chate, AV (corresponding author), Dr Babasaheb Ambedkar Marathwada Univ, Dept Chem, Aurangabad 431004, Maharashtra, India.. The CAS is 100-83-4. Through research, I have a further understanding and discovery of 3-Hydroxybenzaldehyde.

The present work describes eco-friendly multicomponent protocol for the synthesis in excellent yields of structurally diverse benzylpyrazolyl coumarin 5 (a-s) involving the reaction of 4-hydroxycoumarin, ethyl acetoacetate, hydrazine hydrate/phenyl hydrazine hydrate and aldehydes, also novel pyrano[2,3-c]pyrazole derivatives 8 (a-k) integrated by isonicotinic acid hydrazide from reaction of aldehyde, ethyl acetoacetate, malononitrile with isoniazid, employing water as a reaction medium and 2-aminoethanesulfonic acid (taurine) as the catalyst. This new methodology endowed the advantages such as short reaction time, recovery of catalysts after catalytic reaction and reusing them without losing their activity and alleviate of operation. [GRAPHICS] .

Name: 3-Hydroxybenzaldehyde. About 3-Hydroxybenzaldehyde, If you have any questions, you can contact Chate, AV; Shaikh, BA; Bondle, GM; Sangle, SM or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles