Tani, Masanobu’s team published research in Heterocycles in 34 | CAS: 20538-12-9

Heterocycles published new progress about 20538-12-9. 20538-12-9 belongs to indole-building-block, auxiliary class Indole,Ester,Ether, name is Ethyl 7-methoxy-1H-indole-2-carboxylate, and the molecular formula is C5H13Cl2N, Category: indole-building-block.

Tani, Masanobu published the artcileSynthetic studies of indoles and related compounds. XXX. Regioselective bromination of methoxy derivatives of ethyl indole-2-carboxylate, Category: indole-building-block, the publication is Heterocycles (1992), 34(12), 2349-62, database is CAplus.

Bromination of Et methoxyindole-2-carboxylates I (R = H, R1 = 4-, 5-, 6-, 7-OMe) with bromine in acetic acid proceeded on the benzene moiety of I, whereas the reaction of I with pyridinium bromide perbromide in pyridine or N-bromosuccinimide in DMF gave 3-bromo derivatives I (R = Br).

Heterocycles published new progress about 20538-12-9. 20538-12-9 belongs to indole-building-block, auxiliary class Indole,Ester,Ether, name is Ethyl 7-methoxy-1H-indole-2-carboxylate, and the molecular formula is C5H13Cl2N, Category: indole-building-block.

Referemce:
https://www.nature.com/articles/s41429-020-0333-2,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles