Tani, Masanobu’s team published research in Synlett in | CAS: 20538-12-9

Synlett published new progress about 20538-12-9. 20538-12-9 belongs to indole-building-block, auxiliary class Indole,Ester,Ether, name is Ethyl 7-methoxy-1H-indole-2-carboxylate, and the molecular formula is C10H15ClO3S, Category: indole-building-block.

Tani, Masanobu published the artcileSynthetic studies on indoles and related compounds. Part 40. Regioselective and non-reductive C(3)-debromination of indole nucleus, Category: indole-building-block, the publication is Synlett (1996), 931-932, database is CAplus.

A method of debromination of 3-bromoindoles was developed. Various 3-bromoindole-2-carboxylates were treated with H2SO4 and LiBr in AcOH to give the corresponding C(3)-debrominated indoles in excellent yields. The same reaction with 3-bromo-N-tosylindoles gave lower yields.

Synlett published new progress about 20538-12-9. 20538-12-9 belongs to indole-building-block, auxiliary class Indole,Ester,Ether, name is Ethyl 7-methoxy-1H-indole-2-carboxylate, and the molecular formula is C10H15ClO3S, Category: indole-building-block.

Referemce:
https://www.nature.com/articles/s41429-020-0333-2,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles