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Transition Metal Complexes of Diazenes XXXVI [1a]: Formation of Indoles from Azobenzene and Diphenylacetylene through Supported Aqueous Phase Catalysis by Rhodium(I) Complexes

A SiO2 supported Rh(I) catalyst of trisulfonated triphenylphosphine catalyzes the addition of diphenylacetylene to azobenzene in refluxing butanol in the presence of triphenylphosphine to afford N-anilino-2,3-diphenylindole and 2,3-diphenylindole with turnover numbers of 80 and 20, respectively. As compared to the known homogeneous or heterogeneous (SiO2) catalysis by RhCl(PPh3)3, the supported aqueous phase system retains a constant turnover frequency throughout the reaction and can be partially recycled.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles