An article PhIO-Mediated oxidative dethioacetalization/dethioketalization under waterfree conditions WOS:000659043800003 published article about 30-PERCENT HYDROGEN-PEROXIDE; CARBONYL-COMPOUNDS; EFFICIENT DEPROTECTION; REUSABLE CATALYST; CARBOXYLIC-ACIDS; MILD; DITHIOACETALS; 1,3-DITHIANES; PROTOCOL; THIOACETALIZATION in [Yu, Zhenyang; Ouyang, Yaxin; Wang, Xiaofan; Zhao, Bingyue; Wang, Xi; Du, Yunfei] Tianjin Univ, Sch Pharmaceut Sci & Technol, Tianjin Key Lab Modern Drug Delivery & High Effic, Tianjin 300072, Peoples R China; [Zhao, Kang] Shandong Univ, Inst Microbial Technol, State Key Lab Microbial Technol, Qingdao 266237, Peoples R China in 2021, Cited 54. Product Details of 123-11-5. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
Treatment of thioacetals and thioketals with iodosobenzene in anhydrous DCM conveniently afforded the corresponding carbonyl compounds in high yields under water-free conditions. The mechanistic studies indicate that this dethioacetalization/dethioketalization process does not need water and the oxygen of the carbonyl products comes from the hypervalent iodine reagent. [GRAPHICS]
Product Details of 123-11-5. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Yu, ZY; Ouyang, YX; Wang, XF; Zhao, BY; Wang, X; Du, YF; Zhao, K or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles