A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 1986-47-6, Name is trans-2-Phenylcyclopropanamine hydrochloride, molecular formula is C9H12ClN. In an article, author is Mehra, Manish Kumar,once mentioned of 1986-47-6, Quality Control of trans-2-Phenylcyclopropanamine hydrochloride.
Chemoselective Cu-catalyzed synthesis of diverse N-arylindole carboxamides, beta-oxo amides and N-arylindole-3-carbonitriles using diaryliodonium salts
Chemoselective copper-catalyzed synthesis of diverse N-arylindole-3-carboxamides, beta-oxo amides and N-arylindole-3-carbonitriles from readily accessible indole-3-carbonitriles, alpha-cyano ketones and diaryliodonium salts has been developed. Diverse N-arylindole-3-carboxamides and beta-oxo amides were successfully achieved in high yields under copper-catalyzed neutral reaction conditions, and the addition of an organic base (DIPEA) resulted in a completely different selectivity pattern to produce N-arylindole-3-carbonitriles. Moreover, the importance of the developed methodology was realized by the synthesis of indoloquinolones and N-((1H-indol-3-yl)methyl)aniline and by a single-step gram-scale synthesis of the naturally occurring cephalandole A analogue.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles