Category: indole-building-block. Mohanty, SR; Pati, BV; Banjare, SK; Das Adhikari, GK; Ravikumar, PC in [Mohanty, Smruti Ranjan; Pati, Bedadyuti Vedvyas; Banjare, Shyam Kumar; Das Adhikari, Gopal Krushna; Ravikumar, Ponneri Chandrababu] Natl Inst Sci Educ & Res NISER Bhubaneswar, Sch Chem Sci, HBNI, Khurja 752050, Odisha, India published Redox-Neutral Cobalt(III)-Catalyzed C-H Activation/Annulation of alpha,beta-Unsaturated Oxime Ether with Alkyne: One-Step Access to Multisubstituted Pyridine in 2021.0, Cited 43.0. The Name is 3,4-Dimethoxybenzaldehyde. Through research, I have a further understanding and discovery of 120-14-9.
A redox neutral Co(III)-catalyzed annulation of alpha,beta-unsaturated oxime ether with alkyne has been reported. Multisubstituted pyridines were synthesized in good yields without the use of any heavy metal oxidants. The developed methodology tolerates a variety of functional groups. Notably, this transformation has been applied to the late-stage modification of the bioactive molecule dehydropregnenolone.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles