An article Iron-catalysed allylation-hydrogenation sequences as masked alkyl-alkyl cross-couplings WOS:000490283500004 published article about ALKENE HYDROGENATION; GRIGNARD-REAGENTS; COBALT; METAL; TEMPERATURE; SCOPE in [Bernauer, Josef; Wu, Guojiao; Jacobi von Wangelin, Axel] Univ Hamburg, Dept Chem, Martin Luther King Pl 6, D-20146 Hamburg, Germany in 2019, Cited 58. The Name is (E)-2-Methylbut-2-enoic acid. Through research, I have a further understanding and discovery of 80-59-1. Category: indole-building-block
An iron-catalysed allylation of organomagnesium reagents (alkyl, aryl) with simple allyl acetates proceeds under mild conditions (Fe(OAc)(2) or Fe(acac)(2), Et2O, r.t.) to furnish various alkene and styrene derivatives. Mechanistic studies indicate the operation of a homotopic catalyst. The sequential combination of such iron-catalysed allylation with an iron-catalysed hydrogenation results in overall C(sp(3))-C(sp(3))-bond formation that constitutes an attractive alternative to challenging direct cross-coupling protocols with alkyl halides.
About (E)-2-Methylbut-2-enoic acid, If you have any questions, you can contact Bernauer, J; Wu, GJ; Jacobi von Wangelin, A or concate me.. Category: indole-building-block
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles