In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3, S(O)F and Fluorido Complexes, published in 2021-12-15, which mentions a compound: 141556-42-5, mainly applied to mol structure optimized platinum carbene fluoro fluorosulfinyl trifluorosulfur complex; fluorination platinum carbene complex DFT oxidative addition sulfur tetrafluoride; platinum carbene fluoro fluorosulfinyl trifluorosulfur complex preparation; S−F activation; fluorido complexes; fluorine; platinum; sulfur fluorides, Related Products of 141556-42-5.
The electron-rich Pt complex [Pt(IMes)2] (IMes: [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolinylidine]) can be used as precursor for the syntheses of a variety of fluorido ligand containing compounds The sulfur fluoride SF4 undergoes a rapid oxidative addition at Pt0 to yield trans-[Pt(F)(SF3)(IMes)2]. A photolytic reaction of SF6 at [Pt(IMes)2] in the presence of IMes gave the fluorido complexes trans-[Pt(F)2(IMes)2] and trans-[Pt(F)(SF3)(IMes)2] along with trans-[Pt(F)(SOF)(IMes)2] and trans-[Pt(F)(IMes’)(IMes)] (IMes’: cyclometalated IMes ligand), the latter being products produced by reaction with adventitious water. Trans-[Pt(F)(SOF)(IMes)2] and trans-[Pt(F)2(IMes)2] were synthesized independently by treatment of [Pt(IMes)2] with SOF2 or XeF2. A reaction of [Pt(IMes)2] with a HF source gave trans-[Pt(H)(F)(IMes)2], and an intermediate bifluorido complex trans-[Pt(H)(FHF)(IMes)2] was identified. Compound trans-[Pt(H)(F)(IMes)2] converts in the presence of CsF into trans-[Pt(F)(IMes’)(IMes)].
The article 《Fluorination Reactions at a Platinum Carbene Complex: Reaction Routes to SF3, S(O)F and Fluorido Complexes》 also mentions many details about this compound(141556-42-5)Related Products of 141556-42-5, you can pay attention to it, because details determine success or failure
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles