Electric Literature of 303-38-8, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 303-38-8, Name is 2,3-Dihydroxybenzoic acid, SMILES is O=C(O)C1=CC=CC(O)=C1O, belongs to indole-building-block compound. In a article, author is Qin, Yao, introduce new discover of the category.
Rhodium-catalyzed direct C-H amination of 2-arylindoles and 7-arylindoles with free amines
Synthetically meaningful 2-(2′-amino)phenylindoles or 7-(2′-amino)phenylindoles were accessed by rhodium-catalyzed NH-indole-directed C-H amination of 2-aryl-1H-indoles or 7-aryl-1H-indoles with free amines. This method is compatible with a wide variety of functional groups, thus enabling expedient access to fused-polycyclic frameworks containing indole units. (C) 2020 Elsevier Ltd. All rights reserved.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles