An article Nickel-Catalyzed Arylation/Alkenylation of tert-Cyclobutanols with Aryl/Alkenyl Triflates via a C-C Bond Cleavage WOS:000606840200036 published article about CARBON-CARBON BOND; REGIOSPECIFIC SYNTHESIS; ASYMMETRIC ARYLATION; KETONES; ATOM; CYCLOPROPANOLS; CYCLOALKANOLS; ALKYNYLATION; ACTIVATION; GENERATION in [Wang, Zhen; Hu, Yuanyuan; Jin, Hongwei; Liu, Yunkui; Zhou, Bingwei] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China in 2021, Cited 64. Product Details of 150-76-5. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5
Herein, we first present a nickel-catalyzed arylation and alkenylation of tert-cyclobutanols with aryl/alkenyl triflates via a C-C bond cleavage. An array of.-substituted ketones was obtained in moderate-to-good yields, thus featuring earth-abundant nickel catalysis, broad substrate scope, and simple reaction conditions. Preliminary mechanistic experiments indicated that beta-carbon elimination pathways might be involved in the catalytic cycle.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles