Authors Zhou, SH; Dai, FL; Xiang, ZY; Song, T; Liu, DT; Lu, FC; Qi, HS in ELSEVIER SCIENCE BV published article about CATALYTIC TRANSFER HYDROGENATION; LEWIS-ACID SITES; GAMMA-VALEROLACTONE; HETEROGENEOUS CATALYST; METHYL LEVULINATE; CONVERSION; CELLULOSE; ETHERIFICATION; TRANSFORMATION; MICROSPHERES in [Zhou, Shenghui; Dai, Fanglin; Xiang, Zhouyang; Song, Tao; Liu, Detao; Lu, Fachuang; Qi, Haisong] South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510691, Guangdong, Peoples R China; [Lu, Fachuang; Qi, Haisong] Dept Guangdong Engn Res Ctr Green Fine Chem, Guangzhou 510640, Guangdong, Peoples R China in 2019.0, Cited 55.0. SDS of cas: 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Both value-added utilization of low-rank renewable feedstocks to prepare catalytic materials and selective transformation of bioderived aldehydes are very attractive topics. Herein, lignosulfonate, a waste by-product from the paper industry, was simply assembled with ZrCl4 under non-toxic hydrothermal conditions for scalable preparation of Zr-containing polyphenolic biopolymer catalysts (Zr-LS). Systematic characterizations indicated that the strong coordination between Zr4+ and phenolic hydroxyl groups in lignosulfonate led to the formation of strong Lewis acid-base couple sites (Zr4+-O2-) and porous inorganic-organic framework structure (mesopores centered at 6.1 nm), while the inherent sulfonic groups in lignosulphonate could serve as Bronsted acidic sites. The cooperative role of these versatile acid-base sites in Zr-LS afforded excellent catalytic performance for Meerwein-Ponndorf-Verley (MPV) reaction of a broad range of bioderived platform chemicals under mild conditions (80 degrees C), especially of furfural (FF) to furfuryl alcohol (FA), in quantitative yields (96%) with high FA formation rate of 9600 mu mol g(-1)h(-1) and TOF of 4.37 h(-1). Kinetic studies revealed that the activation energy of the MPV reduction of FF was as low as 52.25 kJ/mol, accounting for the high reaction rate. Isotopic labelling experiments demonstrated direct hydrogen transfer from the alpha-C of 2-PrOH to the alpha-C of FF on acid-base sites was the rate-determining step. Moreover, Zr-LS showed good recyclability for at least seven reaction cycles.
SDS of cas: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Zhou, SH; Dai, FL; Xiang, ZY; Song, T; Liu, DT; Lu, FC; Qi, HS or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles