The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane(SMILESS: C1(CC2=N[C@@H](C3=CC=CC=C3)CO2)=N[C@@H](C4=CC=CC=C4)CO1,cas:132098-59-0) is researched.HPLC of Formula: 168106-25-0. The article 《Steric and Electronic Tuning of Chiral Bis(oxazoline) Ligands with 3,3′-Bithiophene Backbone》 in relation to this compound, is published in Journal of Organic Chemistry. Let’s take a look at the latest research on this compound (cas:132098-59-0).
The role played by the electronic properties and the steric features of bis(oxazoline) ligands in the Cu(I)-catalyzed cyclopropanation of styrene effected with Et diazoacetate was investigated. Two pairs of new bis(oxazolines) displaying flexible and atropisomeric 3,3′-bithiophene backbones were synthesized and structurally and electronically characterized. For the first time, the electrochem. oxidative potential was used as a reliable index of the electronic d. on the nitrogen atom of the chelating groups of new and, for comparative purposes, of already known bis(oxazolines). The Cu(I) complexes of the new ligands were prepared, and their enantioselection ability and catalytic efficiency were tested. This investigation suggests that steric factors and catalyst geometrical features are clearly more important than any consideration of the electronic properties of the chiral ligands.
The article 《Steric and Electronic Tuning of Chiral Bis(oxazoline) Ligands with 3,3′-Bithiophene Backbone》 also mentions many details about this compound(132098-59-0)Category: indole-building-block, you can pay attention to it or contacet with the author([email protected]) to get more information.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles