Quality Control of 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene, is researched, Molecular C21H24N2, CAS is 141556-42-5, about N-Heterocyclic carbene, carbodiphosphorane and diphosphine adducts of beryllium dihalides: synthesis, characterisation and reduction studies. Author is Paparo, Albert; Matthews, Aidan J. R.; Smith, Cory D.; Edwards, Alison J.; Yuvaraj, K.; Jones, Cameron.
Reaction of several N-heterocyclic carbenes, a carbodiphosphorane, and bis(diphenylphosphino)ethane (DPPE) with [BeX2(OEt2)2] (X = Br or I) have yielded a variety of Be dihalide adduct complexes, all of which were crystallog. characterized. Attempts to reduce the compounds to low oxidation state Be complexes using a variety of reducing agents were carried out, but were of limited success. However, reaction of [(IPr)BeBr2] (IPr = :C{(DipNCH)2}; Dip = 2,6-diisopropylphenyl) with the Al(I) heterocycle, [:Al(DipNacnac)] (DipNacnac = [HC(MeCNDip)2]-) afforded the adduct complex, [{(IPr)(Br)Be(μ-H)}2], while reduction of [(IPr)BeBr2] with K naphthalenide gave the Be naphthalenediyl complex, [(IPr)Be(C10H8)]. Also, reaction of [{(DPPE)BeI2}∞], with [:Al(DipNacnac)] led to insertion of the Al center of the heterocycle into a Be-I bond, and formation of a rare example of an Al-Be bonded complex, [(DPPE)Be-Al(I)(DipNacnac)].
In some applications, this compound(141556-42-5)Quality Control of 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles