An article Synthesis of coumarins modified with cobalt bis (1,2-dicarbolide) and closo-dodecaborate boron clusters WOS:000548959300011 published article about OXONIUM DERIVATIVES; CARBORANE; DESIGN; ANION in [Kosenko, Irina; Laskova, Julia; Kozlova, Alexandra; Semioshkin, Andrey; Bregadze, Vladimir, I] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilova Str 28, Moscow 119991, Russia in 2020.0, Cited 39.0. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4. Computed Properties of C8H8O2
Synthesis and characterization of novel coumarins containing carborane units were described. The breakdown reactions of cyclic oxonium derivatives of cobalt bis (1,2-dicarbollide) and closo-dodecaborate anions with a series of 7-hydroxy-3-substituted coumarins led to conjugates attached via C-7 position of the coumarin unit. The corresponding reactions of cobalt bis (1,2-dicarbollide) anion with 3-(4-hydroxybenzoyl)-7-methoxy-2H-chromen-2-one led to conjugates attached via C-3 position. Novel conjugates were isolated in the form of alkali metal salts. Therefore, these conjugates are of interest for the fluorescent study in aqua media. (C) 2020 Elsevier B.V. All rights reserved.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles