Recommanded Product: 100-51-6. Recently I am researching about UNACTIVATED C(SP(3))-H; ARYLATION; FUNCTIONALIZATION; LIGAND; GAMMA-C(SP(3))-H; CONSTRUCTION; ALKOXYLATION; ALDEHYDES; AMINES; AMIDE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21602089]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Li, F; Zhou, YR; Yang, H; Wang, ZQ; Yu, QQ; Zhang, FL. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol
We report Pd-catalyzed ortho-C-H methoxylation and chlorination of benzaldehydes by employing monodentate transient directing groups (TDGs) as an alternative strategy to bidentate TDGs. More importantly, a single crystal of benzaldehyde imine ortho-cyclopalladium intermediate was successfully obtained, and its structure was unambiguously determined by X-ray diffraction, which clearly showed that it was a binuclear palladium species bridged by a pyridone ligand. The utility of this approach was further demonstrated through the synthesis of key intermediates of natural products and drugs.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles