Quality Control of Benzyl Alcohol. In 2020 GREEN CHEM published article about SELECTIVE AEROBIC OXIDATION; HYDROGEN-PEROXIDE; ELECTRON-TRANSFER; MOLECULAR-OXYGEN; BUILDING-BLOCKS; IRON CATALYSIS; SOFT OXIDANT; ALDEHYDES; CARBON; SILICOTUNGSTATE in [Wan, Ying; Wu, ZhiKang; Yu, Han; Han, Sheng] Shanghai Inst Technol, Sch Chem & Environm Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China; [Yu, Han; Wei, Yongge] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China; [Yu, Han; Wei, Yongge] Peking Univ, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China in 2020, Cited 51. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Direct catalytic oxidation of alcohols to carboxylic acids is very attractive, but economical catalysis systems have not yet been well established. Here, we show that a pure inorganic ligand-supported chromium compound, (NH4)(3)[CrMo6O18(OH)(6)] (simplified as CrMo6), could be used to effectively promote this type of reaction in the presence of CO2. In almost all cases, oxidation of various alcohols (aromatic and aliphatic) could be achieved under mild conditions, and the corresponding carboxylic acids can be achieved in high yield. The chromium catalyst 1 can be reused several times with little loss of activity. Mechanism study and control reactions demonstrate that the acidification proceeds via the key oxidative immediate of aldehydes.
About Benzyl Alcohol, If you have any questions, you can contact Wan, Y; Wu, ZK; Yu, H; Han, S; Wei, YG or concate me.. Quality Control of Benzyl Alcohol
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles