Authors Li, WK; Cai, Z; Li, H; Shen, Y; Zhu, YQ; Li, HC; Zhang, XB; Wang, FM in ELSEVIER SCIENCE BV published article about TRANSFER HYDROGENATION; ETHYL LEVULINATE; INTEGRATED CONVERSION; PLATFORM MOLECULE; BIOMASS; ACID; ZR; LIQUID; MOFS; FUNCTIONALIZATION in [Li, Wenke; Cai, Zhe; Li, Hang; Shen, Yu; Zhang, Xubin; Wang, Fumin] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China; [Zhu, Yongqiang; Li, Haichao] Qinghai Nationalities Univ, Coll Chem & Chem Engn, Xining 810007, Qinghai, Peoples R China in 2019.0, Cited 57.0. SDS of cas: 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
One-pot conversion of furfural to the target product gamma-valerolactone (GVL) is a challenging and meaningful part of biomass exploitation. Development of heterogeneous catalysts with both Bronsted and Lewis acid properties has proved to be promising and useful because they offer an efficient way to tandem cascade reactions from furfural to GVL. Herein, we successfully synthesized sulfated DUT-67(Hf), a novel bifunctional catalyst, via a post-synthetic modification method. The prepared sulfated DUT-67(Hf) was characterized by XRD, SEM, TEM, N-2 adsorption-desorption, Elemental (N, C, H, S) analyses, situ infrared spectra of pyridine adsorptions, XPS, FTIR, TG, and NH3-TPD. The acidity of the catalysts could be adjusted by submersion in different concentrations of aqueous sulfuric acid, giving 0.01 mol/L sulfuric acid for 0.42 mmol/g acidity to 0.1 mol/L sulfuric acid for 2.16 mmol/g acidity. Sulfated DUT-67(Hf) possessed by 0.06 mol/L aqueous sulfuric acid exhibited optimal catalytic activity and showed an 87.1% yield of GVL under the conditions of 180 degrees C after 24 h of reaction. Moreover, the mechanism of introducing Bronsted acid sites into DUT-67(Hf) and the better hydrogen donors was also investigated through contrasting experiments.
About Benzyl Alcohol, If you have any questions, you can contact Li, WK; Cai, Z; Li, H; Shen, Y; Zhu, YQ; Li, HC; Zhang, XB; Wang, FM or concate me.. SDS of cas: 100-51-6
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles