Application In Synthesis of 4-Methoxybenzaldehyde. Authors Rafferty, SM; Rutherford, JE; Zhang, LM; Wang, L; Nagib, DA in AMER CHEMICAL SOC published article about in [Rafferty, Sean M.; Rutherford, Joy E.; Zhang, Lumin; Wang, Lu; Nagib, David A.] Ohio State Univ, Dept Chem & Biochem, Columbus, OH 43210 USA in 2021.0, Cited 50.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
A cross-selective aza-pinacol coupling of aldehydes and imines has been developed to afford valuable beta-amino alcohols. This strategy enables chemoselective conversion of aliphatic aldehydes to ketyl radicals, in the presence of more easily reduced imines and other functional groups. Upon carbonyl-specific activation by AcI, a photoinitiated Mn catalyst selectively reduces the resulting alpha-oxy iodide by an atom transfer mechanism. The ensuing ketyl radical selectively couples to imines, precluding homodimerization by a classical reductive approach. In this first example of reductive, ketyl coupling by atom transfer catalysis, Zn serves as a terminal reductant to facilitate Mn catalyst turnover. This new strategy also enables ketyl radical couplings to alkenes, alkynes, aldehydes, propellanes, and chiral imines.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles