Product Details of 150-19-6. Recently I am researching about DIFLUOROMETHYL PHENYL SULFONE; RADICAL FLUOROALKYLATION; ORGANOFLUORINE CHEMISTRY; SUBSTITUTION-REACTIONS; FLUORINATED SULFONES; CANNIZZARO REACTION; CARBONYL-COMPOUNDS; TRIFLUOROMETHYLATION; MECHANISM; (PHENYLSULFONYL)DIFLUOROMETHYLATION, Saw an article supported by the National Basic Research Program of ChinaNational Basic Research Program of China [2015CB931900, 2016YFB0101200]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21632009, 21421002]; Key Programs of the Chinese Academy of SciencesChinese Academy of Sciences [KGZD-EW-T08]; Key Research Program of Frontier Sciences of CAS [QYZDJ-SSW-SLH049]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2017T100312]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Xiao, P; Ni, CF; Miao, WJ; Zhou, M; Hu, JY; Chen, DB; Hu, JB. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol
The fluoroalkylation of various nucleophilic reagents with (phenylsulfonyl)difluoromethyl (PhSO2CF2)-substituted phenanthridines was achieved to give fluorinated phenanthridine derivatives, which enables the construction of both carbon-heteroatom and carbon-carbon bonds via the substitution of the phenylsulfonyl group. Mechanistic studies indicated that these reactions proceed through a unimolecular radical nucleophilic substitution (S(RN)1) mechanism. It is worthwhile noting that in the cases of O-nucleophiles (t-BuO- and PhO-), the addition of t-BuOK/PhCHO could significantly promote the reactions, due to the in situ formation of a highly reactive electron donor species through the interaction of t-BuOK, PhCHO, and the solvent DMF, which can effectively initiate the single electron transfer process.
Product Details of 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Xiao, P; Ni, CF; Miao, WJ; Zhou, M; Hu, JY; Chen, DB; Hu, JB or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles