Recommanded Product: Mequinol. In 2021 SCIENCE published article about ARYL ETHERS; AMINO-ALCOHOLS; CLEAVAGE; ACID; ACTIVATION; THERMOCHEMISTRY; DERIVATIVES; MOLECULES; REDUCTION; MECHANISM in [Lyu, Hairong; Yu, Xuan; Dong, Guangbin] Univ Chicago, Dept Chem, Chicago, IL 60637 USA; [Kevlishvili, Ilia; Liu, Peng] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA in 2021, Cited 101. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5.
Mild methods to cleave the carbon-oxygen (C-O) bond in alkyl ethers could simplify chemical syntheses through the elaboration of these robust, readily available precursors. Here we report that dibromoboranes react with alkyl ethers in the presence of a nickel catalyst and zinc reductant to insert boron into the C-O bond. Subsequent reactivity can effect oxygen-to-nitrogen substitution or one-carbon homologation of cyclic ethers and more broadly streamline preparation of bioactive compounds. Mechanistic studies reveal a cleavage-then-rebound pathway via zinc/nickel tandem catalysis.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles