Le Roux, Erwan; Merle, Nicolas; Toernroos, Karl W. published an article about the compound: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane( cas:132098-59-0,SMILESS:C1(CC2=N[C@@H](C3=CC=CC=C3)CO2)=N[C@@H](C4=CC=CC=C4)CO1 ).Application of 132098-59-0. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:132098-59-0) through the article.
A series of zinc(II) alkyl complexes I (1a-c, M = ZnEt) stabilized by the C2-chiral bis(oxazolinato) (HR1,R2BOX) ligands [a, R1 = (4S)-tBu, R2 = H; b, R1 = (4S)-Ph, R2 = H; c, R1 = (4R)-Ph, R2 = (5S)-Ph], has been prepared by metalation of the methylenebis(oxazoline) proligands with diethylzinc and structurally characterized. In an excess of HR1,R2BOX proligands, the homoleptic four-coordinate bis-BOX complexes (2a,b, shown as I2, M = 1/2Zn) were isolated; the crowded ligand c did not give bis-BOX complex. The BOC-ethylzinc complexes 1a-c react readily with protic reagents such as acetic acid (HOAc) and methanol (MeOH). From reaction of 1a,b the homoleptic complexes 2a,b were isolated, resulting from redistribution and formation of Zn acetate, whereas the 1c gave acetato-bridged dimer [3c’, shown as I2, R1 = R2 = Ph, M = (μ-AcO)Zn]. From reaction of 1b with MeOH, the methoxy-bridged complex [4b’, shown as I2, R1 = Ph, R2 = H, M = (μ-MeO)Zn] was obtained, via a three-coordinate complex (4c, shown as I, R1 = Ph, R2 = H, M = ZnOMe). The reaction of acetylacetone (acacH) with compounds 1a-c leads straightforwardly to the more stable four-coordinate compounds I [5a-c, M = Zn(acac)]. The potential of these compounds as initiators for the copolymerization of epoxides with CO2 was investigated.
There is still a lot of research devoted to this compound(SMILES：C1(CC2=N[C@@H](C3=CC=CC=C3)CO2)=N[C@@H](C4=CC=CC=C4)CO1)Application of 132098-59-0, and with the development of science, more effects of this compound(132098-59-0) can be discovered.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles