Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 29046-78-4, is researched, SMILESS is COCCOC.Cl[Ni]Cl, Molecular C4H10Cl2NiO2Journal, Article, Dalton Transactions called Heterobimetallic complexes of IrM (M = FeII, CoII, and NiII) core and bridging 2-(diphenylphosphino)pyridine: electronic structure and electrochemical behavior, Author is Cherepakhin, Valeriy; Hellman, Ashley; Lan, Zhenzhuo; Mallikarjun Sharada, Shaama; Williams, Travis J., the main research direction is heterobimetallic transition metal diphenylphosphinopyridine complex preparation crystal structure; DFT heterobimetallic transition metal diphenylphosphinopyridine complex; cyclic voltammetry heterobimetallic transition metal diphenylphosphinopyridine complex.HPLC of Formula: 29046-78-4.
Three complexes based on an Ir-M (M = FeII, CoII, and NiII) heterobimetallic core and 2-(diphenylphosphino)pyridine (Ph2PPy) ligand were synthesized via the reaction of trans-[IrCl(CO)(Ph2PPy)2] and the corresponding metal chloride. Their structures were established by single-crystal x-ray diffraction as [Ir(CO)(μ-Cl)(μ-Ph2PPy)2FeCl2]·2CH2Cl2 (2), [IrCl(CO)(μ-Ph2PPy)2CoCl2]·2CH2Cl2 (3), and [Ir(CO)(μ-Cl)(μ-Ph2PPy)2NiCl2]·2CH2Cl2 (4). Time-dependent DFT computations suggest a donor-acceptor interaction between a filled 5dz2 orbital on iridium and an empty orbital on the first-row metal atom, which is supported by UV-visible studies. Magnetic moment measurements show that the first-row metals are in their high-spin electronic configurations. Cyclic voltammetry data show that all the complexes undergo irreversible decomposition upon either reduction or oxidation Reduction of 4 proceeds through an ECE mechanism. While these complexes are not stable to electrocatalysis conditions, the data presented here refine the authors’ understanding of the bonding synergies of the first-row and third-row metals.
In some applications, this compound(29046-78-4)HPLC of Formula: 29046-78-4 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles