Recently I am researching about GRAPHITIC CARBON NITRIDE; H2O2 PRODUCTION; SELECTIVE PRODUCTION; OXYGEN REDUCTION; WATER; GENERATION; DOTS; O-2, Saw an article supported by the National MCF Energy RD Program [2018YFE0306105]; National Key Research and Development Project of China [2020YFA0406104, 2017YFA0204800]; Innovative Research Group Project of the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51821002]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51725204, 21771132, 51972216, 52041202]; Natural Science Foundation of Jiangsu ProvinceNatural Science Foundation of Jiangsu Province [BK20190041]; Key-Area Research and Development Program of GuangDong Province [2019B010933001]; Collaborative Innovation Center of Suzhou Nano Science Technology; Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD); 111 ProjectMinistry of Education, China – 111 Project. Recommanded Product: 123-11-5. Published in NATURE RESEARCH in BERLIN ,Authors: Wu, QY; Cao, JJ; Wang, X; Liu, Y; Zhao, YJ; Wang, H; Liu, Y; Huang, H; Liao, F; Shao, MW; Kang, ZH. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde
Artificial photosynthesis of H2O2 from H2O and O-2, as a spotless method, has aroused widespread interest. Up to date, most photocatalysts still suffer from serious salt-deactivated effects with huge consumption of photogenerated charges, which severely limit their wide application. Herein, by using a phenolic condensation approach, carbon dots, organic dye molecule procyanidins and 4-methoxybenzaldehyde are composed into a metal-free photocatalyst for the photosynthetic production of H2O2 in seawater. This catalyst exhibits high photocatalytic ability to produce H2O2 with the yield of 1776 mu mol g(-1)h(-1) (lambda >= 420nm; 34.8mWcm(-2)) in real seawater, about 4.8 times higher than the pure polymer. Combining with in-situ photoelectrochemical and transient photovoltage analysis, the active site and the catalytic mechanism of this composite catalyst in seawater are also clearly clarified. This work opens up an avenue for a highly efficient and practical, available catalyst for H2O2 photoproduction in real seawater. It is a challenge to produce hydrogen peroxide in seawater by photocatalysis. Here, the authors design and synthesize a metal-free photocatalyst based on carbon dots with a salt-protective electron sink effect, which exhibits enhanced hydrogen peroxide photoproduction in real seawater.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles