Category: indole-building-block. In 2020.0 J ORGANOMET CHEM published article about IN-SITU PYROLYSIS; SELECTIVE OXIDATION; BENZYL ALCOHOL; CO2 CAPTURE; MOFS; SEPARATION; ADSORPTION; ALDEHYDES; CAPACITY in [Sabaghi, Maryam; Aghajani, Zahra; Najafi, Gholam Reza] Islamic Azad Univ, Dept Chem, Qom Branch, Qom, Iran in 2020.0, Cited 46.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Ultrasonic-assisted reactions, as a green technique, are often more efficient compared to those traditional protocols. To this end, the selective and solvent-free oxidation of aromatic alcohols to the corresponding aldehydes and ketones were investigated in the presence of Co-ABDC/W at room temperature under ultrasonic irradiation conditions for the first time in this paper. The structure, particle size, thermal stability, and morphology of the fabricated heterogeneous catalyst and the products were characterized by FT-IR, EDS, FE-SEM, XRD, TGA, and GC analyses. In this regard, immobilization of tungstate had a significant effect on thermal stability (around 450 degrees C for 40% weight loss) and catalytic performance. Moreover, the efficiency of two different oxidation methods, including ultrasound irradiations and reflux, were comparatively investigated by GC spectrometry. Obtained sonoxidation results presented higher conversions ranging (84 to 100%) than reflux condition via shorter reaction times. The influences of the reaction parameters, such as hydrogen peroxide concentration, and catalyst loading, were also investigated. The proposed method offers several advantages, such as excellent conversions, selective oxidations, environmentally-benign procedure, short reaction times, and easy workup. Notably, this is the first report that focuses on using amino-functionalized MOFs with ultrasonic irradiation for selective oxidation reactions. (C) 2020 Elsevier B.V. All rights reserved.
Category: indole-building-block. About Benzyl Alcohol, If you have any questions, you can contact Sabaghi, M; Aghajani, Z; Najafi, GR or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles