Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 2208-59-5, is researched, Molecular C12H9N3, about pH-Dependent Assembly of 1D to 3D Octamolybdate Hybrid Materials Based on a New Flexible Bis-[(pyridyl)-benzimidazole] Ligand, the main research direction is pH dependent preparation octamolybdate copper pyridylbenzimidazolebutane polymer; crystal structure octamolybdate copper pyridylbenzimidazolebutane polymer.Synthetic Route of C12H9N3.
Four octamolybdate hybrid materials based on a new flexible multidentate ligand, namely, H4L(γ-Mo8O26)·2H2O (1), [Cu(H2L)(β-Mo8O26)(H2O)2]·3H2O (2), [Cu(H2L)(γ-Mo8O26)]·3H2O (3), and Cu(HL)2(β-Mo8O26) (4), where L is 1,1′-(1,4-butanediyl)bis[2-(4-pyridyl)benzimidazole], were synthesized at different pH values under hydrothermal conditions. Compound 1, which is hydrothermally prepared at pH ≈ 1, exhibits a rare 1-dimensional (1D) Mo oxide chain. Compounds 2 and 3 are hydrothermally obtained at pH ≈ 2.5. In 2, CuII cations are bridged by H2L2+ ligands and (β-Mo8O26)4- anions to form an interesting two-dimensional (2D) layer. In 3, the H2L2+ ligands and (γ-Mo8O26)4- clusters bridge adjacent CuII cations to form a 3-dimensional framework. When the pH value is adjusted to 3.5, compound 4 was obtained. Because the HL+ cation acts as a monodentate ligand, 4 only exhibits a 1-dimensional chain structure. The structural diversities of 1-4 reveal that the pH value of the reaction system plays a crucial role in the assembly of POM-based metal-organic frameworks (MOFs). The electrochem. property of compound 4 also was studied in 1 M H2SO4 aqueous solution
This literature about this compound(2208-59-5)Synthetic Route of C12H9N3has given us a lot of inspiration, and I hope that the research on this compound(2-(Pyridin-4-yl)-1H-benzo[d]imidazole) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles