Name: Benzyl Alcohol. In 2019.0 MACROMOLECULES published article about RING-OPENING POLYMERIZATION; POLYPHOSPHOESTER IONOMERS; POLY(ETHYLENE GLYCOL); BLOCK-COPOLYMERS; POLYMERS; ACID; POLYPHOSPHORAMIDATE; POLY(PHOSPHONATE)S; POLYTHIOESTERS; EFFICIENT in [Liu, Yi; Bejjanki, Naveen Kumar; Jiang, Wei; Zhao, Yangyang; Wang, Li; Sun, Xun; Tang, Xinfeng; Liu, Hang; Wang, Yucai] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Sch Life Sci, Div Mol Med,CAS Key Lab Innate Immun & Chron Dis, Hefei 230026, Anhui, Peoples R China in 2019.0, Cited 42.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
We reported the preparation of well-defined poly(thionophosphoester)s as oxidation-responsive materials that undergo peroxide-triggered degradation. The polymers were synthesized via the controlled ring-opening polymerization of cyclic thionophosphoesters initiated with hydroxyl terminal small molecule and macromolecular initiators and catalyzed with 1,5,7-triazabicyclo[4.4.0]dec-5-ene in tetrahydrofuran at room temperature. The resulting poly-(thionophosphoester)s were characterized in detail by NMR spectroscopy and size exclusion chromatography. Polymerization of cyclic oxophosphoester (P=O) monomers exhibited broad molecular weight distribution and severe side reactions, while narrow molecular weight distribution ((D) over bar (M) similar to 1.1) was achieved without significant transesterifications using thionophosphoester (P=S) monomers. The reaction kinetics of thionophosphoester monomers were in agreement with living polymerization characteristics. Furthermore, by replacing P=O bond by P=S, the polymers changed from hydrophilic to hydrophobic. These well-controlled sulfur-containing polymers are more resistant to hydrolytic degradation but undergo peroxide-triggered degradation. Poly(thionophosphoester)s are thus promising in the field of biomedical materials.
Name: Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Liu, Y; Bejjanki, NK; Jiang, W; Zhao, YY; Wang, L; Sun, X; Tang, XF; Liu, H; Wang, YC or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles