Name: Benzyl Alcohol. Recently I am researching about CATALYZED ESTERIFICATION; CARBOXYLIC-ACIDS; BOND FORMATION; PHENOLS; CONVERSION; CHEMISTRY, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772150]; Wuhan applied fundamental research plan of Wuhan Science and Technology Bureau [2017060201010216]; 111 ProjectMinistry of Education, China – 111 Project; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [2019-YB-001]; Wuhan University of Technology. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Fang, WY; Zha, GF; Qin, HL. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol
We discovered that with the promotion of sulfuryl fluoride, the carbonyl groups of amides performed as nucleophiles while the hydroxyl groups of alcohols were activated to functionalize as electrophiles. This study displayed that the amide C-N bonds could be easily cleaved with delicate nucleophiles to form the ester C-O bonds at room temperature without using transition metals. The broad substrate scope and excellent functional group compatibility were proved with 44 examples in up to 99% yields.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles