SDS of cas: 100-83-4. Recently I am researching about ALPHA-FLUORINATED ETHERS; LASER FLASH-PHOTOLYSIS; TRANSITION-METAL-FREE; ELECTROCHEMICAL OXIDATION; PHOTOREDOX CATALYSIS; ALCOHOL OXIDATION; NITROXYL RADICALS; ELECTRON-TRANSFER; EFFICIENT; CHEMISTRY, Saw an article supported by the NIHUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [R35GM119652]; NSFNational Science Foundation (NSF) [CHE-1827902, CHE-1654122, ACI-1053575]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Lee, JW; Lim, S; Maienshein, DN; Liu, P; Ngai, MY. The CAS is 100-83-4. Through research, I have a further understanding and discovery of 3-Hydroxybenzaldehyde
Applications of TEMPO(.)catalysis for the development of redox-neutral transformations are rare. Reported here is the first TEMPO.-catalyzed, redox-neutral C-H di- and trifluoromethoxylation of (hetero)arenes. The reaction exhibits a broad substrate scope, has high functional-group tolerance, and can be employed for the late-stage functionalization of complex druglike molecules. Kinetic measurements, isolation and resubjection of catalytic intermediates, UV/Vis studies, and DFT calculations support the proposed oxidative TEMPO./TEMPO(+)redox catalytic cycle. Mechanistic studies also suggest that Li(2)CO(3)plays an important role in preventing catalyst deactivation. These findings will provide new insights into the design and development of novel reactions through redox-neutral TEMPO(.)catalysis.
About 3-Hydroxybenzaldehyde, If you have any questions, you can contact Lee, JW; Lim, S; Maienshein, DN; Liu, P; Ngai, MY or concate me.. SDS of cas: 100-83-4
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles