An article Mechanistic Studies on Photoinduced Catalytic Olefin Migration Reactions at the Pd(II) Centers of a Porous Crystal, Metal-Macrocycle Framework WOS:000600657000001 published article about ORGANIC FRAMEWORKS; HYDROGEN STORAGE; ISOMERIZATION; DIMERIZATION; ADSORPTION; ETHYLENE in [Yonezawa, Hirotaka; Han, Mengying; Tashiro, Shohei; Shionoya, Mitsuhiko] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1130033, Japan; [Shiraogawa, Takafumi; Ehara, Masahiro] Inst Mol Sci, Okazaki, Aichi 4448585, Japan; [Shiraogawa, Takafumi; Ehara, Masahiro] SOKENDAI, Okazaki, Aichi 4448585, Japan in 2021.0, Cited 47.0. SDS of cas: 123-11-5. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
Porous crystals with well-defined active metal centers on the pore surface have high potential as heterogeneous metal catalysts. We have recently demonstrated that a porous molecular crystal, metal-macrocycle framework (MMF), catalyzes olefin migration reactions by photoactivation of its (PdCl2)-Cl-II moieties exposed on the crystalline channel surface. Herein we report a mechanistic study of the photoinduced olefin migration reactions at the Pd-II active centers of MMF. Several experiments, including a deuterium scrambling study, revealed that olefin migration is catalyzed via an alkyl mechanism by in situ generated Pd-H species on the channel surface during photoirradiation. This proposed mechanism was further supported by DFT and ONIOM calculations.
About 4-Methoxybenzaldehyde, If you have any questions, you can contact Yonezawa, H; Shiraogawa, T; Han, MY; Tashiro, S; Ehara, M; Shionoya, M or concate me.. SDS of cas: 123-11-5
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